导师姓名

姚子健

导师性别

男

职务职称

教授

所在院系

化工虎扑nba

一级学科

化学

二级学科

无机化学、有机化学

研究方向

配位化学、有机金属化学及有机合成化学

联系电话

电子邮箱

zjyao@sit.edu.cn

个人简介

2014年毕业于复旦大学化学系，获理学博士学位。随后赴美国New York University从事博士后研究，2015年9月进入上海应用技术大学工作。2016年被聘为硕士生导师。近五年以第一作者或通讯作者在J. Am. Chem. Soc., Coord. Chem. Rev., Inorg. Chem., Chem. Commun., Organometallics, Chem. Eur. J.和Dalton Trans等国际著名期刊上发表论文30余篇。申请中国发明专利10项。现作为项目负责人主持国家和省部级项目6项，2017年入选上海市晨光计划，2023年入选上海市曙光计划。

学习与工作经历

1.       国家自然科学基金面上项目，No.22271193，项目负责人

2.       上海市教委曙光计划，No.23SG51，项目负责人

3.       国家自然科学青年基金，No.21601125，项目负责人

4.       上海市自然科学基金，No.16ZR1435700，项目负责人

5.       上海市教委晨光计划，No.16CG64，项目负责人

6.       上海市高校优秀青年教师培养资助计划，项目负责人

7.       上海应用技术大学人才引进启动经费，项目负责人

科研工作与成果

1.Zhi-Jie Wang, Yu-Zhou Luo, Zi-Jian Yao*. Half-Sandwich Ruthenium Complexes With N Phenylpicolinamide Ligands: Preparation and Catalytic Activity in Transamidation Reaction. App. Organomet. Chem. 2025, 39, e7845.

2.Lin-Wu, Ye, Yong Liu, Zi-Jian Yao*. Cyclometalated Half-Sandwich Ruthenium(II) Complexes: Synthesis, Structure, and Catalytic Activity in Imine Synthesis. App. Organomet. Chem. 2025, 39, e70004.

3.Song Gao, Chuan-Qi Cao, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Iridium Complexes: A Recyclable and Stable Catalyst for Dehydrogenation of Alcohols to Carboxylic Acids. Inorg. Chem. 2024, 63, 13311?13320.

4.Lin-Wu Ye, Zi-Jian Yao*. Half-sandwich iridium complexes: Synthesis and catalytic activity in dehydrogenation of alcohols to carboxylic acids. App. Organomet. Chem. 2024, 38, e7642.

5.Song Gao, Chuan-Qi Cao, Zhen-Jiang Liu, Zi-Jian Yao*. Cyclometalated Half-Sandwich Iridium Complexes: Synthesis, Characterization and Catalytic Activity in Preparation of Esters from Halides by Using Formate as Both CO Source and Coupling Partner. App. Organomet. Chem. 2024, 38, e7555.

6.Ke Wang, Song Gao, Yu-Zhou Luo, Zi-Jian Yao*. Synthesis and catalytic activity of half-sandwich iridium complexes with acylhydrazone ligands for N-alkylation of hydrazides under mild conditions. App. Organomet. Chem. 2024, 38, e7473.

7.Heng Li, Ke Wang, Lin Yang, Yu-Zhou Luo, Zi-Jian Yao*. Half-sandwich ruthenium complexes with acylhydrazone ligands: synthesis and catalytic activity in the N-alkylation of hydrazides. Dalton Trans. 2024, 53, 2797?2806.

8.Ke Wang, Heng Li, Lin Yang, Yu-Zhou Luo, Zi-Jian Yao*. Heterogeneous catalytic conversion of carbon dioxide and epoxides to cyclic carbonates. Surfaces and Interfaces 2024, 45, 103845.

9.Lin Yang, Ai-Lin Guan, Zheng-Yang Xu, Zi-Jian Yao*. Cyclometalated Half-Sandwich Ruthenium Complexes: Preparation, Structure, and Catalytic Synthesis of Phenolic Esters from Aryl Halides without Using External CO under Air. Inorg. Chem. 2023, 62, 18198?18208.

10.Yang Wang, Yu-Zhou Luo*, Zhen-Jiang Liu*, Zi-Jian Yao*. Cationic N,S-chelate half-sandwich iridiumcomplexes: synthesis, characterization, anticancer and antiplasmodial activity. Biomater. Sci. 2023, 11, 7090–7098.

11.Ke Wang, Heng Li, Lin Yang, Zhen-Jiang Liu*, Zi-Jian Yao*. Half-Sandwich Ruthenium Complexes with Hydrazone Ligands: Preparation, Structure, and Catalytic Activity in Cyanosilylether Synthesis under an Air Atmosphere. Inorg. Chem. 2023, 62, 9872?9881.

12.Song Gao, Zhen-Jiang Liu, Yu-Zhou Luo*, Zi-Jian Yao*. Half-sandwich iridium complexes with hydrazone ligands: preparation, structure, and catalytic synthesis of cyanosilylethers under air. Dalton Trans. 2023, 52, 11104?11112.

13.Yang Wang, Fang-Lei Zhang, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Iridium Complexes with Hydrazone Ligands: Synthesis and Catalytic Activity in N-Alkylation of Anilines or Nitroarenes with Alcohols via Hydrogen Autotransfer. Inorg. Chem. 2022, 61, 10310?10320.

14.Mengyin Xu, Yang Wang, Yifeng Zhou, Zi-Jian Yao*.N,N-Chelate nickel(II) complexes bearing Schiffbase ligands as efficient hydrogenation catalysts for amine synthesis. J. Organomet. Chem. 2022, 959, 122187.

15.Wen Guo, Zhen-Jiang Liu, Fanhong Wu, Yu-Zhou Luo*, Zi-Jian Yao*. [NN]-Chelate nickel complexes with Schiff base ligands: Synthesis, structure and catalytic activity in green amidation reaction. App. Organomet. Chem. 2022, 36, e6808.

16.Yang Wang, Wen Guo, Ai-Lin Guan, Shuang Liu, Zi-Jian Yao.* Half-Sandwich Iridium Complexes Based on β-Ketoamino Ligands: Preparation, Structure, and Catalytic Activity in Amide Synthesis. Inorg. Chem. 2021, 60, 11514?11520.

17.Wen-Rui Lv, Rong-Jian Li, Zhen-Jiang Liu,* Yan Jin,* Zi-Jian Yao.* Synthesis, Structure, and Catalytic Hydrogenation Activity of [NO]-Chelate Half-Sandwich Iridium Complexes with Schiff Base Ligands. Inorg. Chem. 2021, 60, 8181?8188.

18.Rong-Jian Li, Yang Wang, Yan Jin, Wei Deng, Zhen-Jiang Liu,* Zi-Jian Yao.* NHC Ligand-Based Half-Sandwich Iridium Complexes: Synthesis, Structure and Catalytic Activity in Acceptorless Dehydrogenation and Transfer Hydrogenation. New J. Chem. 2021, 45, 19002?19010.

19.Rong-Jian Li, Chun Ling, Wen-Rui Lv, Wei Deng, Zi-Jian Yao.* Cyclometalated Half-Sandwich Iridium(III) Complexes: Synthesis, Structure and Diverse Catalytic Activity in Imine Synthesis Using Air as Oxidant. Inorg. Chem. 2021, 60, 5153?5162.

20.Yong-Xu Jin, Wei Deng, Zhen-Jiang Liu, Zi-Jian Yao*. Synthesis and Optoelectronic Properties of Cationic Iridium(III) Complexes with o?Carborane- Based 2?Phenyl Benzothiazole Ligands. Inorg. Chem. 2021, 60, 2756?2763.

21.Xue-Jing Yun, Chun Ling, Wei Deng, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Ru(II) Complexes with N,O-Chelate Ligands: Diverse Catalytic Activity for Amine Synthesis in Water. Organometallics 2020, 39, 3830?3838.

22.Xiao-Nan Fan, Wei Deng, Zhen-Jiang Liu, Zi-Jian Yao*. Half-Sandwich Iridium Complexes for One-Pot Synthesis of Amides: Preparation, Structure and Diverse Catalytic Activity. Inorg. Chem. 2020, 59, 16582?16590.

23.Xue-Jing Yun, Jing-Wei Zhu, Yan Jin, Wei Deng, Zi-Jian Yao*. Half-Sandwich Ruthenium Complexes for One-Pot Synthesis of Quinolines and Tetrahydroquinolines: Diverse Catalytic Activity in the Coupled Cyclization and Hydrogenation Process. Inorg. Chem. 2020, 59, 7841?7851.

24.Xiao-Nan Fan, Hui-Dan Ou, Wei Deng, Zi-Jian Yao*. Air-Stable Half-Sandwich Iridium Complexes as Aerobic Oxidation Catalysts for Imine Synthesis. Inorg. Chem. 2020, 59, 4800?4809.

25.Jing-Wei Zhu, Hui-Dan Ou, Niwei Xu, Wei Deng*, Zi-Jian Yao*. Ruthenium-based phosphorescent probe for selective and naked-eye detection of cyanide in aqueous media. Dyes and Pigments. 2020, 176, 108196.

26.Nan Lin, Hui-Dan Ou, Qiyan Xu*, Yan Jin*, Wei Deng, Zi-Jian Yao*. An Efficient Probe of Cyclometallated Phosphorescent Iridium Complex for Selective Detection of Cyanide. ACS Omega. 2020, 5, 4636?4645. (Front cover)

27.Zi-Jian Yao*, Jing-Wei Zhu, Nan Lin, Xin-Chao Qiao, Wei Deng*. Catalytic Hydrogenation of Carbonyl and Nitro Compounds Using [NO]-chelate Half-Sandwich Ruthenium Catalyst. Dalton Trans. 2019, 48, 7158?7166.

28.Peng Li, Jin-Bao Liu, Sheng Han, Wei Deng*, Zi-Jian Yao*. Half-sandwich Ir(III) and Rh(III) complexes as catalysts for water oxidation with double-site. App. Organomet. Chem. 2019, 33, e5040.

29.Xin-Chao Qiao, Dan-Chen Qiu, Nan Lin, Jing-Wei Zhu, Wei Deng, Zi-Jian Yao*. Half-Sandwich Ruthenium-Based Versatile Catalyst for Both Alcohol Oxidation and Catalytic Hydrogenation of Carbonyl Compounds in Aqueous Media. App. Organomet. Chem. 2019, 33, e4875.

30.Peng Li, Yi-Mei Xu, Wei Deng*, Zi-Jian Yao*. Self-assembly of supramolecular coordination complexes based on half-sandwich metal corner with tunable host cavities. J. Organomet. Chem. 2019, 884, 36?43.

31.Zi-Jian Yao*, Nan Lin, Xin-Chao Qiao, Jing-Wei Zhu, Wei Deng*. Cyclometalated Half-Sandwich Iridium Complex for Catalytic Hydrogenation of Imines and Quinolines. Organometallics 2018, 37, 3883.

32.Zi-Jian Yao*, Peng Li, Kuan Li, Wei Deng*. Synthesis, structure and catalytic polymerization activity of half‐sandwich cyclometallated iridium complexes. App. Organomet. Chem. 2018, 32, e4239.

社会学术团体兼职

中国化学会高级会员，美国化学会会员

主要研究方向

近3年指导研究生的就业情况

累计指导研究生25名，其中，在校生8名。