导师介绍 | |||||||||||||||||||||||
导师姓名 | 刘超 |
| |||||||||||||||||||||
导师性别 | 男 | ||||||||||||||||||||||
职务职称 | 教授 | ||||||||||||||||||||||
所在院系 | 化学与环境工程虎扑nba | ||||||||||||||||||||||
一级学科 | 化学工程与技术 | ||||||||||||||||||||||
二级学科 | 化学工程 | ||||||||||||||||||||||
研究方向 | 有机氟化学 | ||||||||||||||||||||||
联系电话 | 021-60877227 | ||||||||||||||||||||||
电子邮箱 | chaoliu@sit.edu.cn | ||||||||||||||||||||||
个人简介 | |||||||||||||||||||||||
主要从事绿色氟代技术研究，围绕绿色高效合成含氟有机化合物的研究主题，发展具有特色和创新性的新型氟烷基化试剂、反应及策略，用于含氟医药和材料的研发和绿色生产。作为负责人主持国家自然科学基金青年项目1项、国家自然科学基金面上项目1项、上海市自然科学基金项目1项和河南省科技开放合作项目1项，承担了多项企业合作项目，并作为主要完成人参与了多项国家重大科研项目研究。已在J. Am. Chem. Soc.、Angew. Chem., Int. Ed.、Org. Lett.等国际著名期刊上发表SCI研究论文40余篇，他引逾千次。还获得授权专利6篇，受邀撰写英文专著章节1篇。研究成果受到国际同行广泛关注，先后得到Synfacts、Chin. J. Org. Chem.等多家媒体杂志的推荐和报道。 | |||||||||||||||||||||||
学习与工作经历 | |||||||||||||||||||||||
| |||||||||||||||||||||||
科研工作与成果 | |||||||||||||||||||||||
近五年代表性论文： 1. Arenesulfonyl Fluoride Synthesis via Copper-catalyzed Fluorosulfonylation of Arenediazonium Salts. Chao Liu* et. al., Org. Lett. 2020, 22, 2281-2286. 2. Cobalt-Catalyzed Radical Hydrotrifluoroethylation of Styrenes with Trifluoroethyl Iodide. Chao Liu* et. al.,Org. Lett. 2020, 22, 6552?6556. 3. Zinc-mediated Intermolecular Reductive Radical Fluoroalkylsulfination of Unsaturated Carbon-Carbon Bonds with Fluoroalkyl bromides and Sulfur Dioxide. Chao Liu* et. al.,Chem. Eur. J. 2019, 25, 1824-1828. ( Hot paper) 4. Intermolecular Oxidative Radical Fluoroalkylfluorosulfonylation of Unactivated Alkenes with (Fluoroalkyl)trimethylsilane, Silver Fluoride, Sulfur Dioxide and N-fluorobenzenesulfonimide. Chao Liu* et. al., Org. Chem. Front. 2019, 6, 447-450. 5. Oxidative Radical Intermolecular Trifluoromethylthioarylation of Styrenes by Arenediazonium Salts and Copper(I) Trifluoromethylthiolate. Chao Liu* et. al.,J. Org. Chem.2018, 83, 5836-5843. 6. Oxidative Radical Phosphonotrifluoromethylthiolation of Unactivated Alkenes with Alkyl Phosphonate, Silver(I) Trifluoromethanethiolate and Potassium Persulfate. Chao Liu* et. al., Tetrahedron2018, 74, 6213-6219 (Invited). 7. Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O2CCF2SO2F) and N-Fluorobenzenesulfonimide. Chao Liu* et. al., Angew. Chem., Int. Ed. 2017, 56, 15432-15435. Highlighted by Synfacts 2018, 14, 0071. Chin. J. Org. Chem. 2018, 38, 982. 8. Oxidative Decarboxylative Radical Trifluoromethylthiolation of Alkyl Carboxylic Acids with Silver(I) Trifluoromethanethiolate and Selectfluor.Chao Liu* et. al.,RSC Adv.2017, 7, 880-883. 9. Trifluoromethylation of Haloarenes with a New Trifluoromethylating Reagent Cu(O2CCF2SO2F)2. Chao Liu* et. al.,RSC Adv.2016, 6, 50250-50254. 10. Direct Trifluoromethylthiolation of Unactivated C(sp3)-H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate. Chao Liu* et. al., Angew. Chem., Int. Ed.2015, 54, 4070-4074. Highlighted by Chin. J. Org. Chem. 2015, 35, 1185. | |||||||||||||||||||||||
社会学术团体兼职 | |||||||||||||||||||||||
无 | |||||||||||||||||||||||
主要研究方向 | |||||||||||||||||||||||
三氟甲基化、三氟甲硫基化、氟磺酰基化、氟烷氧基化新试剂及反应的开发和研究 | |||||||||||||||||||||||
近3年指导研究生的就业情况 | |||||||||||||||||||||||
法国巴黎大学博士研究生（国家公派留学奖学金），博士后（同济大学、美国哈佛医虎扑nba） | |||||||||||||||||||||||
